Gold(I)-catalyzed amination of allylic alcohols with cyclic ureas and related nucleophiles.
نویسندگان
چکیده
A 1:1 mixture of [P(t-Bu)(2)-o-biphenyl]AuCl and AgSbF(6) catalyzes the intermolecular amination of allylic alcohols with 1-methylimidazolidin-2-one and related nucleophiles that, in the case of gamma-unsubstituted or gamma-methyl-substituted allylic alcohols, occurs with high gamma-regioselectivity and syn-stereoselectivity.
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ورودعنوان ژورنال:
- Organic letters
دوره 12 6 شماره
صفحات -
تاریخ انتشار 2010